yo diría, leyendo su hoja de datos, que no es posible:
9.0 MASTER SYNCHRONOUS SERIAL PORT (MSSP) MODULE
The Master Synchronous Serial Port (MSSP) module is a serial interface, useful for communicating with other peripheral or microcontroller devices. These peripheral devices may be serial EEPROMs, shift registers, display drivers, A/D converters, etc. The MSSP module can operate in one of two modes:
• Serial Peripheral Interface (SPI)
• Inter-Integrated Circuit (I2C)
Figure 9-1 shows a block diagram for the SPI mode, while Figure 9-5 and Figure 9-9 show the block diagrams for the two different I2C modes of operation. (página 65).
no sé si mediante programación se pueden simultanear a la velocidad suficiente a tus necesidades...
un saludo